Friday, June 20, 2014

Biomolecules — Carbohydrates

Carbohydrates are the most abundant biomolecule in nature. 


Function of carbohydrates
  • building blocks for larger molecules 
  • energy storage — starch (plant) and glycogen (animal)
  • structural — cellulose cell wall (plant) and chitin (insects, crabs, shrimps)
The bond between monomers of carbohydrates is known as glycosidic bond.

Monosaccharides
  • monomers of carbohydrates
  • eg. glucose, fructose, galactose
  • all monosaccharides are reducing sugars
Disaccharides
  • made up of two monosaccharides

http://i.imgur.com/2Kx8x.jpg
Polysaccharides
  • made up of many monosaccharides
What is starch? 
  • polymer of glucose molecules
  • has two components; amylose and amylopectin
  • both fit together to form a complex 3-dimensional structure which is insoluble in water
  • amylose helices are entangled in the branches of amylopectin molecules
  • each amylose chain is coiled into a helix, with six glucose residues for every complete turn of the helix — compact shape making it a complex structure for storage
  • amylopectin have many branches

What is glycogen?
  • animal equivalent of starch
  • found in liver and skeletal muscles of vertebrate animals 

Starch and glycogen (energy stores)
  • their molecules have many side branches where glucose molecules can be removed from their tips (by enzymes)
  • their insolubility stops them interfering with osmosis
  • their compactness provides an efficient way to store lots of glucose for future cellular respiration

Cellulose (long, unbranched chain)
  • most abundant organic molecule on Earth
  • major component of cell wall in plants
  • made from long, straight unbranched chains of glucose
  • chains cross-linked by H-bonds which holds them tightly together (excludes water)
  • chemically very inert and insoluble 
  • many molecules form strong fibrils
  • only some bacteria, fungi and a very small number of animals can secrete cellulase enzymes

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